2H Solid-State NMR Investigation of Terephthalate Dynamics and Orientation inMixed-Anion Hydrotalcite-Like Compounds
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چکیده
منابع مشابه
Solid-state NMR as a probe of anion binding: molecular dynamics and associations in a [5]polynorbornane bisurea host complexed with terephthalate.
A range of solid-state NMR techniques is used to characterise a molecular host:guest complex consisting of a [5]polynorbornane bisurea host binding a terephthalate dianion guest. Detailed information is obtained on the molecular dynamics and associations from the point of view of both the host and guest molecules. The formation of the complex in the solid state is confirmed using (1)H 2D exchan...
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Molecular dynamics (MD) simulation of the Mg/Al (3:1) layered double hydroxide (LDH), hydrotalcite (HT), containing citrate, C6H5O7(3-), as the charge balancing interlayer anion provides new molecular scale insight into the interlayer structure, hydrogen bonding, and energetics of the hydration and consequent swelling of LDH compounds containing organic and biomolecules. Citrate-HT exhibits aff...
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-Ion-exchange isotherms between hydrotalcite-like compounds (HT) of the NO3-, CI-, and SO4forms and F , 0% Br , I , OH-, SO42-, CO3 z-, and Naphthol Yellow S (NYS 2-) ions were determined, and the spacing and the width of the 003 reflection were measured as a function of HT composition. The ion-exchange equilibrium constant for HTs of monovalent anions are in the sequence OH> F > Cl > Br> NO3> ...
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